Migratory functionalization of unactivated alkyl bromides for construction of all-carbon quaternary centers via transposed tert-C-radicals

Despite remarkable recent advances in transition-metal-catalyzed C(sp(3))−C cross-coupling reactions, there remain challenging bond formations. One class of such reactions include the formation of tertiary-C(sp(3))−C bonds, presumably due to unfavorable steric interactions and competing isomerizatio...

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Detalles Bibliográficos
Autores principales: Zhu, Chuan, Liu, Ze-Yao, Tang, Luning, Zhang, Heng, Zhang, Yu-Feng, Walsh, Patrick J., Feng, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7519689/
https://www.ncbi.nlm.nih.gov/pubmed/32978381
http://dx.doi.org/10.1038/s41467-020-18658-4

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7519689/
https://www.ncbi.nlm.nih.gov/pubmed/32978381
http://dx.doi.org/10.1038/s41467-020-18658-4

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