Ruthenium(II)-Catalyzed Homocoupling of α-Carbonyl Sulfoxonium Ylides Under Mild Conditions: Methodology Development and Mechanistic DFT Study

A mild ruthenium(II)-catalyzed homocoupling of α-carbonyl sulfoxonium ylides was developed and the detailed mechanism was understood based on DFT calculations in the current report. The catalytic system utilizes the α-carbonyl sulfoxonium ylide as both the directing group for ortho-sp(2) C-H activat...

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Detalles Bibliográficos
Autores principales: Zhang, Maosheng, Zhang, Jinrong, Teng, Zhenfang, Chen, Jianhui, Xia, Yuanzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7525066/
https://www.ncbi.nlm.nih.gov/pubmed/33195001
http://dx.doi.org/10.3389/fchem.2020.00648

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7525066/
https://www.ncbi.nlm.nih.gov/pubmed/33195001
http://dx.doi.org/10.3389/fchem.2020.00648

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