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A robust and tunable halogen bond organocatalyzed 2-deoxyglycosylation involving quantum tunneling

The development of noncovalent halogen bonding (XB) catalysis is rapidly gaining traction, as isolated reports documented better performance than the well-established hydrogen bonding thiourea catalysis. However, convincing cases allowing XB activation to be competitive in challenging bond formation...

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Detalles Bibliográficos
Autores principales: Xu, Chunfa, Rao, V. U. Bhaskara, Weigen, Julia, Loh, Charles C. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7527348/
https://www.ncbi.nlm.nih.gov/pubmed/32999276
http://dx.doi.org/10.1038/s41467-020-18595-2