Application of NMR Spectroscopy for the Detection of Equilibrating E–Z Diastereomers

[Image: see text] Conjugation can lower the energy barrier for unsaturated C–C bond rotations, resulting in a mixture of equilibrating diastereomers at room temperature. Therefore, methods claiming diastereoselective synthesis of conjugated double bonds often require proof that the observed diastere...

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Detalles Bibliográficos
Autores principales: Hussaini, Syed Raziullah, Kuta, Adama, Pal, Arpan, Wang, Zhiguo, Eastman, Margaret A., Duran, Ramon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7528312/
https://www.ncbi.nlm.nih.gov/pubmed/33015503
http://dx.doi.org/10.1021/acsomega.0c03554

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7528312/
https://www.ncbi.nlm.nih.gov/pubmed/33015503
http://dx.doi.org/10.1021/acsomega.0c03554

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