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Application of NMR Spectroscopy for the Detection of Equilibrating E–Z Diastereomers
[Image: see text] Conjugation can lower the energy barrier for unsaturated C–C bond rotations, resulting in a mixture of equilibrating diastereomers at room temperature. Therefore, methods claiming diastereoselective synthesis of conjugated double bonds often require proof that the observed diastere...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7528312/ https://www.ncbi.nlm.nih.gov/pubmed/33015503 http://dx.doi.org/10.1021/acsomega.0c03554 |