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Crystal structures of [μ(2)-(R(a),S(a),3aR,7aR)-1,3-bis(2,7-dicyclohexylnaphthalen-1-yl)octahydro-1H-benzo[d]imidazolidin-2-ylidene]chlorido(η(4)-1,5-cyclooctadiene)iridium dichloromethane monosolvate and [μ(2)-(S(a),S(a),3aR,7aR)-1,3-bis(2,7-dicyclohexylnaphthalen-1-yl)octahydro-1H-benzo[d]imidazolidin-2-ylidene]chlorido(η(4)-1,5-cyclooctadiene)iridium
The title compounds, [Ir(C(51)H(64)N(2))Cl(C(8)H(12))]·CH(2)Cl(2), (I), and [Ir(C(51)H(64)N(2))Cl(C(8)H(12))], (II), represent the first two examples of hexahydrobenzoimidazole-based N-heterocyclic carbene (NHC) iridium complexes. The diastereomeric complexes differing only in their axial chirali...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7534235/ https://www.ncbi.nlm.nih.gov/pubmed/33117560 http://dx.doi.org/10.1107/S2056989020011603 |