Crystal structures of [μ(2)-(R(a),S(a),3aR,7aR)-1,3-bis­(2,7-di­cyclo­hexyl­naphthalen-1-yl)octa­hydro-1H-benzo[d]imidazolidin-2-yl­idene]chlorido­(η(4)-1,5-cyclo­octa­diene)iridium di­chloro­methane monosolvate and [μ(2)-(S(a),S(a),3aR,7aR)-1,3-bis­(2,7-di­cyclo­hexyl­naphthalen-1-yl)octa­hydro-1H-benzo[d]imidazolidin-2-yl­idene]chlorido­(η(4)-1,5-cyclo­octa­diene)iridium

The title compounds, [Ir(C(51)H(64)N(2))Cl(C(8)H(12))]·CH(2)Cl(2), (I), and [Ir(C(51)H(64)N(2))Cl(C(8)H(12))], (II), represent the first two examples of hexa­hydro­benzo­imidazole-based N-heterocyclic carbene (NHC) iridium complexes. The diastereomeric complexes differing only in their axial chirali...

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Detalles Bibliográficos
Autores principales: Moggach, Stephen A., Skelton, Brian W., Foster, Daven J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7534235/
https://www.ncbi.nlm.nih.gov/pubmed/33117560
http://dx.doi.org/10.1107/S2056989020011603

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