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Synthesis and Characterization of a Novel Triangular Rh(2)Au Cluster Compound Inspired by the Isolobality Concept

The synthesis of [Rh(2)(η(5)‐Cp)(2)(μ‐H)(μ‐PPh(2))(2)]BF(4) (2) by protonation reaction of the metal basic complex [Rh(2)(η(5)‐Cp)(2)(μ‐PPh(2))(2)] (1) with tetrafluoroboric acid in diethyl ether is described. Complex salt 2 was obtained in high yield and fully characterized by spectroscopic means a...

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Detalles Bibliográficos
Autores principales: Böttcher, Hans‐Christian, Graf, Marion, Mayer, Peter, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7536363/
https://www.ncbi.nlm.nih.gov/pubmed/33042726
http://dx.doi.org/10.1002/open.202000217