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Catalytic trifluoromethylation of iodoarenes by use of 2-trifluoromethylated benzimidazoline as trifluoromethylating reagent

The trifluoromethylation of iodoarenes was accomplished by use of a 2-trifluoromethylbenzimidazoline derivative as the trifluoromethylating reagent and a catalytic amount of Cu(I) in the presence of 2,2'-bipyridyl as the ligand. Through a mechanistic study, we found that the oxidative addition...

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Detalles Bibliográficos
Autores principales: Uchikura, Tatsuhiro, Kamiyama, Nanami, Ishikawa, Taisuke, Akiyama, Takahiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7537379/
https://www.ncbi.nlm.nih.gov/pubmed/33082878
http://dx.doi.org/10.3762/bjoc.16.198