Tackling N‐Alkyl Imines with 3d Metal Catalysis: Highly Enantioselective Iron‐Catalyzed Synthesis of α‐Chiral Amines

A readily activated iron alkyl precatalyst effectively catalyzes the highly enantioselective hydroboration of N‐alkyl imines. Employing a chiral bis(oxazolinylmethylidene)isoindoline pincer ligand, the asymmetric reduction of various acyclic N‐alkyl imines provided the corresponding α‐chiral amines...

Descripción completa

Detalles Bibliográficos
Autores principales: Blasius, Clemens K., Heinrich, Niklas F., Vasilenko, Vladislav, Gade, Lutz H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7539954/
https://www.ncbi.nlm.nih.gov/pubmed/32453491
http://dx.doi.org/10.1002/anie.202006557

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7539954/
https://www.ncbi.nlm.nih.gov/pubmed/32453491
http://dx.doi.org/10.1002/anie.202006557

Ejemplares similares