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Tackling N‐Alkyl Imines with 3d Metal Catalysis: Highly Enantioselective Iron‐Catalyzed Synthesis of α‐Chiral Amines

A readily activated iron alkyl precatalyst effectively catalyzes the highly enantioselective hydroboration of N‐alkyl imines. Employing a chiral bis(oxazolinylmethylidene)isoindoline pincer ligand, the asymmetric reduction of various acyclic N‐alkyl imines provided the corresponding α‐chiral amines...

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Detalles Bibliográficos
Autores principales:	Blasius, Clemens K., Heinrich, Niklas F., Vasilenko, Vladislav, Gade, Lutz H.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7539954/ https://www.ncbi.nlm.nih.gov/pubmed/32453491 http://dx.doi.org/10.1002/anie.202006557

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