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Iron in a Cage: Fixation of a Fe(II)tpy(2) Complex by Fourfold Interlinking

The coordination sphere of the Fe(II) terpyridine complex 1 is rigidified by fourfold interlinking of both terpyridine ligands. Profiting from an octa‐aldehyde precursor complex, the ideal dimensions of the interlinking structures are determined by reversible Schiff‐base formation, before irreversib...

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Detalles Bibliográficos
Autores principales: Brandl, Thomas, Johannsen, Sven, Häussinger, Daniel, Suryadevara, Nithin, Prescimone, Alessandro, Bernhard, Stefan, Gruber, Manuel, Ruben, Mario, Berndt, Richard, Mayor, Marcel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540000/
https://www.ncbi.nlm.nih.gov/pubmed/32412664
http://dx.doi.org/10.1002/anie.202006340