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Innovative Syntheses of Cyano(fluoro)borates: Catalytic Cyanation, Electrochemical and Electrophilic Fluorination

Different types of high‐yield, easily scalable syntheses for cyano(fluoro)borates Kt[BF(n)(CN)(4−n)] (n=0–2) (Kt=cation), which are versatile building blocks for materials applications and chemical synthesis, have been developed. Tetrafluoroborates react with trimethylsilyl cyanide in the presence o...

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Detalles Bibliográficos
Autores principales: Drisch, Michael, Bischoff, Lisa A., Sprenger, Jan A. P., Hennig, Philipp T., Wirthensohn, Raphael, Landmann, Johannes, Konieczka, Szymon Z., Hailmann, Michael, Ignat'ev, Nikolai V., Finze, Maik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540003/
https://www.ncbi.nlm.nih.gov/pubmed/32453869
http://dx.doi.org/10.1002/chem.202002324