Cargando…

Innovative Syntheses of Cyano(fluoro)borates: Catalytic Cyanation, Electrochemical and Electrophilic Fluorination

Different types of high‐yield, easily scalable syntheses for cyano(fluoro)borates Kt[BF(n)(CN)(4−n)] (n=0–2) (Kt=cation), which are versatile building blocks for materials applications and chemical synthesis, have been developed. Tetrafluoroborates react with trimethylsilyl cyanide in the presence o...

Descripción completa

Detalles Bibliográficos
Autores principales:	Drisch, Michael, Bischoff, Lisa A., Sprenger, Jan A. P., Hennig, Philipp T., Wirthensohn, Raphael, Landmann, Johannes, Konieczka, Szymon Z., Hailmann, Michael, Ignat'ev, Nikolai V., Finze, Maik
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540003/ https://www.ncbi.nlm.nih.gov/pubmed/32453869 http://dx.doi.org/10.1002/chem.202002324

Ejemplares similares

Borylation of fluorinated arenes using the boron-centred nucleophile B(CN)(3) (2–) – a unique entry to aryltricyanoborates
por: Landmann, Johannes, et al.
Publicado: (2017)

Pentafluoroethylaluminates: A Combined Synthetic, Spectroscopic, and Structural Study
por: Bischoff, Lisa A., et al.
Publicado: (2020)

2-Cyanoanilinium tetrafluoroborate
por: Zhang, Yi
Publicado: (2009)

5‐(Cyano)dibenzothiophenium Triflate: A Sulfur‐Based Reagent for Electrophilic Cyanation and Cyanocyclizations
por: Li, Xiangdong, et al.
Publicado: (2019)

Dismutation of Tricyanoboryllead Compounds: The Homoleptic Tetrakis(tricyanoboryl)plumbate Tetraanion
por: Häring, Mathias, et al.
Publicado: (2022)

Crystal structure of 2-cyano-1-methylpyridinium tetrafluoroborate
por: Vaccaro, Francesca A., et al.
Publicado: (2015)

Stable and Storable N(CF(3))(2) Transfer Reagents
por: Schneider, Leon N., et al.
Publicado: (2021)

Boron: Its Role in Energy‐Related Processes and Applications
por: Huang, Zhenguo, et al.
Publicado: (2020)

Trimethylsulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodecaborate
por: Finze, Maik, et al.
Publicado: (2012)

Tris(pentafluoroethyl)difluorophosphorane: A Versatile Fluoride Acceptor for Transition Metal Chemistry
por: Föhrenbacher, Steffen A., et al.
Publicado: (2021)

2-Azaniumylcarba-closo-dodecaborate ethanol monosolvate
por: Himmelspach, Alexander, et al.
Publicado: (2011)

1-Cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane tetrafluoroborate monohydrate
por: Cai, Ying
Publicado: (2010)

Cyanomethanaminium tetrafluoroborate
por: Han, Meng Ting, et al.
Publicado: (2010)

Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine
por: Han, Jianlin, et al.
Publicado: (2020)

Strontium tetrafluoroborate. Erratum
por: Goreshnik, Evgeny, et al.
Publicado: (2010)

Sodium pentafluorophenylborate
por: Vitze, Hannes, et al.
Publicado: (2012)

Kinetics of Electrophilic Fluorination of Steroids and Epimerisation of Fluorosteroids
por: Rozatian, Neshat, et al.
Publicado: (2020)

1-Butylquinine tetrafluoroborate
por: Eltaief, Sana, et al.
Publicado: (2010)

Tetraethylammonium 12-phenylethynylcarba-closo-dodecaborate, [Et(4)N][12-PhCC-closo-CB(11)H(11)]
por: Finze, Maik, et al.
Publicado: (2009)

A quantitative reactivity scale for electrophilic fluorinating reagents
por: Rozatian, Neshat, et al.
Publicado: (2018)

Ionic Liquid-Assisted Grinding: An Electrophilic Fluorination Benchmark
por: Zaikin, Pavel A., et al.
Publicado: (2021)

Fluorocarbyne complexes via electrophilic fluorination of carbido ligands
por: Manzano, Richard A., et al.
Publicado: (2023)

The low-temperature phase of morpholinium tetrafluoroborate
por: Owczarek, Magdalena, et al.
Publicado: (2008)

Crystallographic characterization of rare-earth cyanotriphenylborate complexes and the cyanoborates [NCBPh(3)](1−), [NCBPh(2)Me](1−), and [NCBPh(2)(μ-O)BPh(2)](1−)
por: Dumas, Megan T., et al.
Publicado: (2021)

Fractal-Percolation Structure Architectonics in Sol-Gel Synthesis
por: Kononova, Irina, et al.
Publicado: (2021)

Insights into structure–property relationships in ionic liquids using cyclic perfluoroalkylsulfonylimides
por: Bejaoui, Younes K. J., et al.
Publicado: (2023)

Tetraethylammonium 7,12-dicyano-1-carba-closo-dodecaborate
por: Juhasz, Marcus A., et al.
Publicado: (2014)

2,3,5,6-Tetrafluoro-1,4-bis(trimethylsilyl)benzene
por: Finze, Maik, et al.
Publicado: (2012)

Synthesis of Fluorinated 3,6-Dihydropyridines and 2-(Fluoromethyl)pyridines by Electrophilic Fluorination of 1,2-Dihydropyridines with Selectfluor(®)
por: Pikun, Nadiia V., et al.
Publicado: (2020)

Tris(2-benzamidoethyl)ammonium tetrafluoroborate
por: Pilate, Marcy L., et al.
Publicado: (2010)

Benzylammonium tetrafluoroborate 18-crown-6 clathrate
por: Zhao, Min Min
Publicado: (2010)

One-pot regioselective C–H activation iodination–cyanation of 2,4-diarylquinazolines using malononitrile as a cyano source
por: Yan, Ziqiao, et al.
Publicado: (2019)

Tetrapyrazineplatinum(II) bis(tetrafluoroborate) acetonitrile hemisolvate
por: Derry, Paul J., et al.
Publicado: (2008)

4-Chloroanilinium tetrafluoroborate 18-crown-6 clathrate
por: Xu, Jie, et al.
Publicado: (2012)

2-[(Diisopropylthiophosphoryl)amino]pyridinium tetrafluoroborate
por: Holzhacker, Christian, et al.
Publicado: (2012)

4-Methylanilinium tetrafluoroborate 18-crown-6 clathrate
por: Ge, Jia-Zhen, et al.
Publicado: (2010)

A Convenient Synthesis of Triflate Anion Ionic Liquids and Their Properties
por: Ignat’ev, Nikolai V., et al.
Publicado: (2012)

Nickel‐Catalyzed, Reductive C(sp(3))−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes
por: Zhang, Liangliang, et al.
Publicado: (2021)

Preparation, properties, and technology of fluorine and organic fluoro compounds
por: Slesser, Charles
Publicado: (1951)

1-Benzyl-3-(2-methoxyphenyl)imidazolium tetrafluoroborate
por: Jiang, Ping
Publicado: (2009)

Cannot write session to /tmp/vufind_sessions/sess_5c32jvt5hj19dmuf8196fgla6l