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A Cationic NHC‐Supported Borole

This work describes the synthesis and characterization of a highly reactive cationic borole. Halide abstraction with Li{Al[OC(CF(3))(3)](4)} from the NHC‐chloroborole adduct yields the first stable NHC‐supported 1‐((Me)NHC)‐2,5‐(SiMe(3))(2)‐3,4‐(Ph*)(2)‐borole cation. Electronically, it features bot...

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Detalles Bibliográficos
Autores principales: Heitkemper, Tobias, Sindlinger, Christian P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540045/
https://www.ncbi.nlm.nih.gov/pubmed/32343437
http://dx.doi.org/10.1002/chem.202001916