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A Cationic NHC‐Supported Borole
This work describes the synthesis and characterization of a highly reactive cationic borole. Halide abstraction with Li{Al[OC(CF(3))(3)](4)} from the NHC‐chloroborole adduct yields the first stable NHC‐supported 1‐((Me)NHC)‐2,5‐(SiMe(3))(2)‐3,4‐(Ph*)(2)‐borole cation. Electronically, it features bot...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540045/ https://www.ncbi.nlm.nih.gov/pubmed/32343437 http://dx.doi.org/10.1002/chem.202001916 |