Enhancing Tris(pyrazolyl)borate‐Based Models of Cysteine/Cysteamine Dioxygenases through Steric Effects: Increased Reactivities, Full Product Characterization and Hints to Initial Superoxide Formation

The design of biomimetic model complexes for the cysteine dioxygenase (CDO) and cysteamine dioxygenase (ADO) is reported, where the 3‐His coordination of the iron ion is simulated by three pyrazole donors of a trispyrazolyl borate ligand (Tp) and protected cysteine and cysteamine represent substrate...

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Detalles Bibliográficos
Autores principales: Müller, Lars, Hoof, Santina, Keck, Matthias, Herwig, Christian, Limberg, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540079/
https://www.ncbi.nlm.nih.gov/pubmed/32432367
http://dx.doi.org/10.1002/chem.202001818

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540079/
https://www.ncbi.nlm.nih.gov/pubmed/32432367
http://dx.doi.org/10.1002/chem.202001818

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