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Enhancing Tris(pyrazolyl)borate‐Based Models of Cysteine/Cysteamine Dioxygenases through Steric Effects: Increased Reactivities, Full Product Characterization and Hints to Initial Superoxide Formation
The design of biomimetic model complexes for the cysteine dioxygenase (CDO) and cysteamine dioxygenase (ADO) is reported, where the 3‐His coordination of the iron ion is simulated by three pyrazole donors of a trispyrazolyl borate ligand (Tp) and protected cysteine and cysteamine represent substrate...
Autores principales: | Müller, Lars, Hoof, Santina, Keck, Matthias, Herwig, Christian, Limberg, Christian |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540079/ https://www.ncbi.nlm.nih.gov/pubmed/32432367 http://dx.doi.org/10.1002/chem.202001818 |
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