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Metal–Ligand Cooperativity of the Calix[4]pyrrolato Aluminate: Triggerable C−C Bond Formation and Rate Control in Catalysis
Metal‐ligand cooperativity (MLC) had a remarkable impact on transition metal chemistry and catalysis. By use of the calix[4]pyrrolato aluminate, [1](−), which features a square‐planar Al(III), we transfer this concept into the p‐block and fully elucidate its mechanisms by experiment and theory. Comp...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540271/ https://www.ncbi.nlm.nih.gov/pubmed/32573936 http://dx.doi.org/10.1002/anie.202007717 |