The First Use of a ReX(5) Synthon to Modulate Fe(III) Spin Crossover via Supramolecular Halogen⋅⋅⋅Halogen Interactions

We have added the {Re(IV)X(5)}(−) (X=Br, Cl) synthon to a pocket‐based ligand to provide supramolecular design using halogen⋅⋅⋅halogen interactions within an Fe(III) system that has the potential to undergo spin crossover (SCO). By removing the solvent from the crystal lattice, we “switch on” haloge...

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Detalles Bibliográficos
Autores principales: Busch, Rebecca, Carter, Anthony B., Konidaris, Konstantis F., Kühne, Irina A., González, Ricardo, Anson, Christopher E., Powell, Annie K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540276/
https://www.ncbi.nlm.nih.gov/pubmed/32267564
http://dx.doi.org/10.1002/chem.202001668

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540276/
https://www.ncbi.nlm.nih.gov/pubmed/32267564
http://dx.doi.org/10.1002/chem.202001668

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