Cargando…
The First Use of a ReX(5) Synthon to Modulate Fe(III) Spin Crossover via Supramolecular Halogen⋅⋅⋅Halogen Interactions
We have added the {Re(IV)X(5)}(−) (X=Br, Cl) synthon to a pocket‐based ligand to provide supramolecular design using halogen⋅⋅⋅halogen interactions within an Fe(III) system that has the potential to undergo spin crossover (SCO). By removing the solvent from the crystal lattice, we “switch on” haloge...
| Autores principales: | , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540276/ https://www.ncbi.nlm.nih.gov/pubmed/32267564 http://dx.doi.org/10.1002/chem.202001668 |