Improved Access to Organo‐Soluble Di‐ and Tetrafluoridochlorate(I)/(III) Salts

A facile one‐pot gram‐scale synthesis of tetraalkylammonium tetrafluoridochlorate(III) [cat][ClF(4)] ([cat]=[NEt(3)Me](+), [NEt(4)](+)) is described. An acetonitrile solution of the corresponding alkylammonium chloride salt is fluorinated with diluted fluorine at low temperatures. The reaction proce...

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Detalles Bibliográficos
Autores principales: Pröhm, P., Schmid, J. R., Sonnenberg, K., Voßnacker, P., Steinhauer, S., Schattenberg, C. J., Müller, R., Kaupp, M., Riedel, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540313/
https://www.ncbi.nlm.nih.gov/pubmed/32459871
http://dx.doi.org/10.1002/anie.202006268

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540313/
https://www.ncbi.nlm.nih.gov/pubmed/32459871
http://dx.doi.org/10.1002/anie.202006268

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