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Atom Exchange Versus Reconstruction: (Ge(x)As(4−x))(x−) (x=2, 3) as Building Blocks for the Supertetrahedral Zintl Cluster [Au(6)(Ge(3)As)(Ge(2)As(2))(3)](3−)
The Zintl anion (Ge(2)As(2))(2−) represents an isostructural and isoelectronic binary counterpart of yellow arsenic, yet without being studied with the same intensity so far. Upon introducing [(PPh(3))AuMe] into the 1,2‐diaminoethane (en) solution of (Ge(2)As(2))(2−), the heterometallic cluster anio...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540319/ https://www.ncbi.nlm.nih.gov/pubmed/32648322 http://dx.doi.org/10.1002/anie.202008108 |