Cargando…

Atom Exchange Versus Reconstruction: (Ge(x)As(4−x))(x−) (x=2, 3) as Building Blocks for the Supertetrahedral Zintl Cluster [Au(6)(Ge(3)As)(Ge(2)As(2))(3)](3−)

The Zintl anion (Ge(2)As(2))(2−) represents an isostructural and isoelectronic binary counterpart of yellow arsenic, yet without being studied with the same intensity so far. Upon introducing [(PPh(3))AuMe] into the 1,2‐diaminoethane (en) solution of (Ge(2)As(2))(2−), the heterometallic cluster anio...

Descripción completa

Detalles Bibliográficos
Autores principales: Pan, Fuxing, Guggolz, Lukas, Weigend, Florian, Dehnen, Stefanie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540319/
https://www.ncbi.nlm.nih.gov/pubmed/32648322
http://dx.doi.org/10.1002/anie.202008108

Ejemplares similares