α‐Amidoaldehydes as Substrates in Rhodium‐Catalyzed Intermolecular Alkyne Hydroacylation: The Synthesis of α‐Amidoketones

We show that readily available α‐amidoaldehydes are effective substrates for intermolecular Rh‐catalyzed alkyne hydroacylation reactions. The catalyst [Rh(dppe)(C(6)H(5)F)][BAr(F) (4)] provides good reactivity, and allows a broad range of aldehydes and alkynes to be used as substrates, delivering α‐...

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Detalles Bibliográficos
Autores principales: Pal, Ritashree, O'Brien, Sean C., Willis, Michael C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540332/
https://www.ncbi.nlm.nih.gov/pubmed/32449532
http://dx.doi.org/10.1002/chem.202002478

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540332/
https://www.ncbi.nlm.nih.gov/pubmed/32449532
http://dx.doi.org/10.1002/chem.202002478

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