An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair

The geminal frustrated Lewis pair (F(5)C(2))(3)SnCH(2)P(tBu)(2) (1) reacted with N‐sulfinylaniline PhNSO to afford the first sulfur monoxide adduct of a main group metal, (F(5)C(2))(3)SnCH(2)P(tBu)(2)⋅SO (2), which contains a SnCPSO ring. The second product is a phenylnitrene adduct of 1. The surpri...

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Detalles Bibliográficos
Autores principales: Holtkamp, Philipp, Glodde, Timo, Poier, Dario, Neumann, Beate, Stammler, Hans‐Georg, Mitzel, Norbert W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540458/
https://www.ncbi.nlm.nih.gov/pubmed/32558235
http://dx.doi.org/10.1002/anie.202007653

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540458/
https://www.ncbi.nlm.nih.gov/pubmed/32558235
http://dx.doi.org/10.1002/anie.202007653

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