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Quantifying Through‐Space Substituent Effects

The description of substituents as electron donating or withdrawing leads to a perceived dominance of through‐bond influences. The situation is compounded by the challenge of separating through‐bond and through‐space contributions. Here, we probe the experimental significance of through‐space substi...

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Detalles Bibliográficos
Autores principales: Burns, Rebecca J., Mati, Ioulia K., Muchowska, Kamila B., Adam, Catherine, Cockroft, Scott L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540488/
https://www.ncbi.nlm.nih.gov/pubmed/32542910
http://dx.doi.org/10.1002/anie.202006943