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Photochemical Approach to the Cyclohepta[b]indole Scaffold by Annulative Two‐Carbon Ring‐Expansion

We report on the implementation of the concept of a photochemically elicited two‐carbon homologation of a π‐donor–π‐acceptor substituted chromophore by triple‐bond insertion. Implementing a phenyl connector between the slide‐in module and the chromophore enabled the synthesis of cylohepta[b]indole‐t...

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Detalles Bibliográficos
Autores principales: Tymann, Dina Christina, Benedix, Lars, Iovkova, Lyuba, Pallach, Roman, Henke, Sebastian, Tymann, David, Hiersemann, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540574/
https://www.ncbi.nlm.nih.gov/pubmed/32463529
http://dx.doi.org/10.1002/chem.202002581