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The Butterfly Complex [{Cp*Cr(CO)(3)}(2)(μ,η(1:1)‐P(4))] as a Versatile Ligand and Its Unexpected P(1)/P(3) Fragmentation
The versatile coordination behavior of the P(4) butterfly complex [{Cp*Cr(CO)(3)}(2)(μ,η(1:1)‐P(4))] (1) towards Lewis acidic pentacarbonyl compounds of Cr, Mo and W is reported. The reaction of 1 with [W(CO)(4)(nbd)] (nbd=norbornadiene) yields the complex [{Cp*Cr(CO)(3)}(2)(μ(3),η(1:1:1:1)‐P(4)){W(...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540658/ https://www.ncbi.nlm.nih.gov/pubmed/32657480 http://dx.doi.org/10.1002/chem.202002957 |