Cargando…

The Butterfly Complex [{Cp*Cr(CO)(3)}(2)(μ,η(1:1)‐P(4))] as a Versatile Ligand and Its Unexpected P(1)/P(3) Fragmentation

The versatile coordination behavior of the P(4) butterfly complex [{Cp*Cr(CO)(3)}(2)(μ,η(1:1)‐P(4))] (1) towards Lewis acidic pentacarbonyl compounds of Cr, Mo and W is reported. The reaction of 1 with [W(CO)(4)(nbd)] (nbd=norbornadiene) yields the complex [{Cp*Cr(CO)(3)}(2)(μ(3),η(1:1:1:1)‐P(4)){W(...

Descripción completa

Detalles Bibliográficos
Autores principales:	Grünbauer, Rebecca, Balázs, Gábor, Scheer, Manfred
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540658/ https://www.ncbi.nlm.nih.gov/pubmed/32657480 http://dx.doi.org/10.1002/chem.202002957

Ejemplares similares

Halogenation of the Hexaphosphabenzene Complex [(Cp*Mo)(2)(μ,η(6):η(6)‐P(6))]: Snapshots on the Reaction Progress
por: Garbagnati, Anna, et al.
Publicado: (2022)

Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo)(2)(μ,η(6):η(6)-P(6))] Towards the “Naked” Cations Cu(+), Ag(+), and Tl(+)
por: Fleischmann, Martin, et al.
Publicado: (2015)

Controlled introduction of functional groups at one P atom in [Cp*Fe(η(5)-P(5))] and release of functionalised phosphines
por: Reichl, Stephan, et al.
Publicado: (2023)

The Triple-Decker Complex [Cp*Fe(µ,η(5):η(5)-P(5))Mo(CO)(3)] as a Building Block in Coordination Chemistry
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2019)

Transformations of the cyclo-P(4) ligand in [Cp′′′Co(η(4)-P(4))]
por: Piesch, Martin, et al.
Publicado: (2020)

catena-Poly[{μ-η(5):η(5)-1-[2-(dimethylamino)ethyl-κN]cyclopentadienyl}-lithium(I)-(μ-1,1,3,3-tetra-tert-butyltriphosphane-κ(3) P (2):P (1),P (3))lithium(I)]
por: Grubba, Rafal, et al.
Publicado: (2010)

Crystal structure of the [(THF)Cs(μ-η(5):η(5)-Cp′)(3)Yb](n) oligomer
por: Huh, Daniel N., et al.
Publicado: (2020)

Coordination Behavior of [Cp″(2)Zr(µ(1:1)-As(4))] towards Lewis Acids
por: Heinl, Veronika, et al.
Publicado: (2021)

Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp(2)Mo(2)(CO)(4)(η(2)‐P(2))] Complex and Silver(I) Salts
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2017)

An Inverted-Sandwich Diuranium μ-η(5):η(5)-Cyclo-P(5) Complex Supported by U-P(5) δ-Bonding**
por: Gardner, Benedict M, et al.
Publicado: (2015)

An Inverted‐Sandwich Diuranium μ‐η(5):η(5)‐Cyclo‐P(5) Complex Supported by U‐P(5) δ‐Bonding
por: Gardner, Benedict M., et al.
Publicado: (2015)

Metalate‐Mediated Functionalization of P(4) by Trapping Anionic [Cp*Fe(CO)(2)(η(1)‐P(4))](−) with Lewis Acids
por: Borger, Jaap E., et al.
Publicado: (2017)

The Missing Parent Compound [(C(5)H(5))Fe(η(5)‐P(5))]: Synthesis, Characterization, Coordination Behavior and Encapsulation
por: Heinl, Claudia, et al.
Publicado: (2021)

Bis[1,3(η(3))-allyl][μ-2(η(4))-1,3-bis(diphenylphosphino)-2,4-diphenylcyclobuta-1,3-diene-1:3κ(2) P:P′]dichlorido-1κCl,3κCl-[2(η(5))-isopropylcyclopentadienyl]-2-cobalt(I)-1,3-dipalladium(II) dichloromethane solvate
por: Chang, Chin-Pei, et al.
Publicado: (2009)

Stabilization of Pentaphospholes as η(5)‐Coordinating Ligands
por: Riesinger, Christoph, et al.
Publicado: (2020)

Bis{[(η(5))-cyclopentadienyl]tris(diethyl phosphito-κ(3) P,P′,P′′)cobaltate(III)-κ(3) O,O′,O′′]oxovanadium(IV)}-μ-oxalate
por: McLauchlan, Craig C., et al.
Publicado: (2008)

The Potential of the Diphosphorus Complex [Cp(2)W(2)(CO)(4)(η(2)‐P(2))] as an Organometallic Connecter in Supramolecular Chemistry
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2019)

Steric Switching From Photochemical to Thermal N(2) Splitting: A Computational Analysis of the Isomerization Reaction {(Cp(*))(Am)Mo}(2)(μ-η(1):η(1)-N(2)) → {(Cp(*))(Am)Mo}(2)(μ-N)(2)
por: Krewald, Vera
Publicado: (2019)

Diantimony Complexes [Cp(R) (2)Mo(2)(CO)(4)(μ,η(2)‐Sb(2))] (Cp(R)=C(5)H(5), C(5)H(4) (t)Bu) as Unexpected Ligands Stabilizing Silver(I)( n ) (n=1–4) Monomers, Dimers and Chains
por: Shelyganov, Pavel A., et al.
Publicado: (2023)

Mixed Organometallic–Organic Hybrid Assemblies Based on the Diarsene Complex [Cp(2)Mo(2)(CO)(4)(μ,η(2)‐As(2))], Ag(I) Salts and N‐Donor Organic Molecules
por: Elsayed Moussa, Mehdi, et al.
Publicado: (2021)

Bis[μ-1,2-bis(diphenylphosphino)methane-κ(2) P:P′]bis[(η(2)-ethene)nickel(0)] toluene disolvate
por: Langer, Jens, et al.
Publicado: (2008)

The Diphosphorus Complex [Cp(2)Mo(2)(CO)(4)(η(2)‐P(2))] as a Building Block for the Synthesis of Mixed‐Hybrid Coordination Polymers
por: Moussa, Mehdi Elsayed, et al.
Publicado: (2016)

Tris[μ-1,2-bis(diphenylphosphino)ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate
por: Shi, Wen-Juan
Publicado: (2008)

Giant Rugby Ball [{Cp(Bn)Fe(η(5)-P(5))}(24)Cu(96)Br(96)] Derived from Pentaphosphaferrocene and CuBr(2)
por: Heindl, Claudia, et al.
Publicado: (2015)

Comparison of the catalytic activity for the Suzuki–Miyaura reaction of (η(5)-Cp)Pd(IPr)Cl with (η(3)-cinnamyl)Pd(IPr)(Cl) and (η(3)-1-t-Bu-indenyl)Pd(IPr)(Cl)
por: Melvin, Patrick R, et al.
Publicado: (2015)

The Potential of the Diarsene Complex [(C(5)H(5))(2)Mo(2)(CO)(4)(μ,η(2)‐As(2))] as a Connector Between Silver Ions
por: Moussa, Mehdi Elsayed, et al.
Publicado: (2020)

Synthesis and Multiple Subsequent Reactivity of Anionic cyclo‐E(3) Ligand Complexes (E=P, As)
por: Piesch, Martin, et al.
Publicado: (2021)

[μ-1,3-Bis(diphenylphosphino)propane-κ(2) P:P′]bis[bromidogold(I)]
por: Mohr, Fabian, et al.
Publicado: (2010)

An Actinide Zintl Cluster: A Tris(triamidouranium)μ(3)-η(2):η(2):η(2)-Heptaphosphanortricyclane and Its Diverse Synthetic Utility**
por: Patel, Dipti, et al.
Publicado: (2013)

Coordination Chemistry of P(4)S(3) and P(4)Se(3) towards the Iron Fragments [Fe(Cp)(CO)(2)](+) and [Fe(Cp)(PPh(3))(CO)](+)
por: Weis, Philippe, et al.
Publicado: (2019)

Identification of LSD analogs, 1cP-AL-LAD, 1cP-MIPLA, 1V-LSD and LSZ in sheet products
por: Tanaka, Rie, et al.
Publicado: (2023)

(Carbonyl-1κC)bis[2,3(η(5))-cyclopentadienyl][μ(3)-(S-methyl trithiocarbonato)methylidyne-1:2:3κ(4) C,S′′:C:C](triphenylphosphine-1κP)(μ(3)-sulfido-1:2:3κ(3) S)dicobalt(II)iron(II) trifluoromethanesulfonate
por: Manning, Anthony R., et al.
Publicado: (2008)

LHCb searches for the strong CP-violating decays η → ππ and η′ → ππ
por: Capriotti, L
Publicado: (2017)

1,3-Bis(2-thienylmethyl)-4,5-dihydroimidazolium trichlorido(η(6)-p-cymene)ruthenate(II)
por: Arslan, Hakan, et al.
Publicado: (2009)

Coordination Behavior of a P(4)‐Butterfly Complex towards Transition Metal Lewis Acids: Preservation versus Rearrangement
por: Müller, Julian, et al.
Publicado: (2021)

(μ(3)-Hydrido)[μ(3)-2-(trimethylsilyl)ethylidyne-κ(3) C (1):C (1):C (1)]tetrakis[(η(5)-cyclopentadienyl)cobalt(II)]
por: Haehnel, Martin, et al.
Publicado: (2013)

Substituted aromatic pentaphosphole ligands – a journey across the p-block
por: Riesinger, Christoph, et al.
Publicado: (2021)

[μ-3,3′-Diisopropyl-1,1′-(propane-1,3-diyl)bis(1,3-diazinan-2-ylidene)]bis[bromido(η(4)-cycloocta-1,5-diene)rhodium(I)]
por: Pawar, Gajanan Manohar, et al.
Publicado: (2014)

[1,4-Bis(diphenylphosphanyl)butane-κ(2) P,P′]chlorido(η(5)-indenyl)ruthenium(II)
por: Sung, Hui-Ling, et al.
Publicado: (2011)

Azido[1,2-bis(diphenylphosphanyl)ethane-κ(2) P,P′](η(5)-indenyl)ruthenium(II)
por: Sung, Hui-Ling, et al.
Publicado: (2010)

Cannot write session to /tmp/vufind_sessions/sess_kr11ims26id94ekuldhm3emcbv