Emergence of a New [NNN] Pincer Ligand via Si−H Bond Activation and β‐Hydride Abstraction at Tetravalent Cerium

The cerium(IV) pyrazolate complexes [Ce(Me(2)pz)(4)](2) and [Ce(Me(2)pz)(4)(thf)] initiate β‐hydride abstraction of the bis(dimethylsilyl)amido moiety, to afford a heteroleptic cerium(IV) species containing a dimethylpyrazolyl‐substituted silylamido ligand, namely [Ce(Me(2)pz)(3)(bpsa)] (bpsa=bis((3...

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Detalles Bibliográficos
Autores principales: Werner, Daniel, Bayer, Uwe, Schädle, Dorothea, Anwander, Reiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540680/
https://www.ncbi.nlm.nih.gov/pubmed/32239686
http://dx.doi.org/10.1002/chem.202000625

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540680/
https://www.ncbi.nlm.nih.gov/pubmed/32239686
http://dx.doi.org/10.1002/chem.202000625

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