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Emergence of a New [NNN] Pincer Ligand via Si−H Bond Activation and β‐Hydride Abstraction at Tetravalent Cerium
The cerium(IV) pyrazolate complexes [Ce(Me(2)pz)(4)](2) and [Ce(Me(2)pz)(4)(thf)] initiate β‐hydride abstraction of the bis(dimethylsilyl)amido moiety, to afford a heteroleptic cerium(IV) species containing a dimethylpyrazolyl‐substituted silylamido ligand, namely [Ce(Me(2)pz)(3)(bpsa)] (bpsa=bis((3...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540680/ https://www.ncbi.nlm.nih.gov/pubmed/32239686 http://dx.doi.org/10.1002/chem.202000625 |