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Second Comes First: Switching Elementary Steps in Palladium‐Catalyzed Cross‐Coupling Reactions
The electron‐poor palladium(0) complex L(3)Pd (L=tris[3,5‐bis(trifluoromethyl)phenyl]phosphine) reacts with Grignard reagents RMgX and organolithium compounds RLi via transmetalation to furnish the anionic organopalladates [L(2)PdR](−), as shown by negative‐ion mode electrospray‐ionization mass spec...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540703/ https://www.ncbi.nlm.nih.gov/pubmed/32428266 http://dx.doi.org/10.1002/chem.202001041 |