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Second Comes First: Switching Elementary Steps in Palladium‐Catalyzed Cross‐Coupling Reactions

The electron‐poor palladium(0) complex L(3)Pd (L=tris[3,5‐bis(trifluoromethyl)phenyl]phosphine) reacts with Grignard reagents RMgX and organolithium compounds RLi via transmetalation to furnish the anionic organopalladates [L(2)PdR](−), as shown by negative‐ion mode electrospray‐ionization mass spec...

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Detalles Bibliográficos
Autores principales:	Kolter, Marlene, Koszinowski, Konrad
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540703/ https://www.ncbi.nlm.nih.gov/pubmed/32428266 http://dx.doi.org/10.1002/chem.202001041

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