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Total Synthesis of (+)-Petromyroxol, (−)-iso-Petromyroxol, and Possible Diastereomers

[Image: see text] The total synthesis of (+)-petromyroxol (1) and its seven diastereomers including the (−)-iso-petromyroxol (2) is described. The employed strategy involves the use of easily available C5-epimeric epoxides 5 and 5′ and nonselective anomeric C1-allylation, proceeding with or without...

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Detalles Bibliográficos
Autores principales: Mullapudi, Venkannababu, Ahmad, Iram, Senapati, Sibadatta, Ramana, Chepuri V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7542842/
https://www.ncbi.nlm.nih.gov/pubmed/33043213
http://dx.doi.org/10.1021/acsomega.0c03674