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Total Synthesis of (+)-Petromyroxol, (−)-iso-Petromyroxol, and Possible Diastereomers
[Image: see text] The total synthesis of (+)-petromyroxol (1) and its seven diastereomers including the (−)-iso-petromyroxol (2) is described. The employed strategy involves the use of easily available C5-epimeric epoxides 5 and 5′ and nonselective anomeric C1-allylation, proceeding with or without...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7542842/ https://www.ncbi.nlm.nih.gov/pubmed/33043213 http://dx.doi.org/10.1021/acsomega.0c03674 |