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A Concise Route for the Synthesis of Tetracyclic Meroterpenoids: (±)-Aureol Preparation and Mechanistic Interpretation

A new concise general methodology for the synthesis of different tetracyclic meroterpenoids is reported: (±)-aureol (1), the key intermediate of this general route. The synthesis of (±)-aureol (1) was achieved in seven steps (28% overall yield) from (±)-albicanol. The key steps of this route include...

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Detalles Bibliográficos
Autores principales: Rosales Martínez, Antonio, Enríquez, Lourdes, Jaraíz, Martín, Pozo Morales, Laura, Rodríguez-García, Ignacio, Díaz Ojeda, Emilio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7551916/
https://www.ncbi.nlm.nih.gov/pubmed/32858988
http://dx.doi.org/10.3390/md18090441