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Water Loss from Protonated XxxSer and XxxThr Dipeptides Gives Oxazoline—Not Oxazolone—Product Ions

[Image: see text] Neutral loss of water and ammonia are often significant fragmentation channels upon collisional activation of protonated peptides. Here, we deploy infrared ion spectroscopy to investigate the dehydration reactions of protonated AlaSer, AlaThr, GlySer, GlyThr, PheSer, PheThr, ProSer...

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Detalles Bibliográficos
Autores principales: Oomens, Jos, Kempkes, Lisanne J. M., Geurts, Thijs P. J., van Dijk, Luuk, Martens, Jonathan, Berden, Giel, Armentrout, P. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7552115/
https://www.ncbi.nlm.nih.gov/pubmed/32876444
http://dx.doi.org/10.1021/jasms.0c00239