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Stabilizing a metalloid {Zn(12)} unit within a polymetallide environment in [K(2)Zn(20)Bi(16)](6−)
The access to molecules comprising direct Zn–Zn bonds has become very topical in recent years for various reasons. Low-valent organozinc compounds show remarkable reactivities, and larger Zn–Zn-bonded gas-phase species exhibit a very unusual coexistence of insulating and metallic properties. However...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7552394/ https://www.ncbi.nlm.nih.gov/pubmed/33046705 http://dx.doi.org/10.1038/s41467-020-18799-6 |