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Transition-State Expansion: A Quantitative Model for Counterion Effects in Ionic Reactions

Ionic reactions are the most common reactions used in chemical synthesis. In relatively low dielectric constant solvents (e.g., dichloromethane, toluene), ions usually exist as ion pairs. Despite the importance of counterions, a quantitative description of how the paired 'counterion' affec...

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Detalles Bibliográficos
Autores principales: Han, Junbin, Lu, Zhichao, Hammond, Gerald B., Xu, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7554029/
https://www.ncbi.nlm.nih.gov/pubmed/33083752
http://dx.doi.org/10.1016/j.isci.2020.101593