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Transition-State Expansion: A Quantitative Model for Counterion Effects in Ionic Reactions
Ionic reactions are the most common reactions used in chemical synthesis. In relatively low dielectric constant solvents (e.g., dichloromethane, toluene), ions usually exist as ion pairs. Despite the importance of counterions, a quantitative description of how the paired 'counterion' affec...
Autores principales: | Han, Junbin, Lu, Zhichao, Hammond, Gerald B., Xu, Bo |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7554029/ https://www.ncbi.nlm.nih.gov/pubmed/33083752 http://dx.doi.org/10.1016/j.isci.2020.101593 |
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