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Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane Precursors
[Image: see text] Quantum chemical calculations were used to determine the energetic viability of several mechanisms for formation of ladderanes from oligocyclopropanes. Pathways involving radical cations, diradicals, and carbocations were considered, and a hybrid of carbocation and radical cation p...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7558033/ https://www.ncbi.nlm.nih.gov/pubmed/33073141 http://dx.doi.org/10.1021/acsomega.0c03735 |