Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane Precursors

[Image: see text] Quantum chemical calculations were used to determine the energetic viability of several mechanisms for formation of ladderanes from oligocyclopropanes. Pathways involving radical cations, diradicals, and carbocations were considered, and a hybrid of carbocation and radical cation p...

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Detalles Bibliográficos
Autores principales: Chen, Shu-Sen, Tantillo, Dean J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7558033/
https://www.ncbi.nlm.nih.gov/pubmed/33073141
http://dx.doi.org/10.1021/acsomega.0c03735
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author Chen, Shu-Sen
Tantillo, Dean J.
author_facet Chen, Shu-Sen
Tantillo, Dean J.
author_sort Chen, Shu-Sen
collection PubMed
description [Image: see text] Quantum chemical calculations were used to determine the energetic viability of several mechanisms for formation of ladderanes from oligocyclopropanes. Pathways involving radical cations, diradicals, and carbocations were considered, and a hybrid of carbocation and radical cation pathways was predicted to have the lowest overall barrier.
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spelling pubmed-75580332020-10-16 Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane Precursors Chen, Shu-Sen Tantillo, Dean J. ACS Omega [Image: see text] Quantum chemical calculations were used to determine the energetic viability of several mechanisms for formation of ladderanes from oligocyclopropanes. Pathways involving radical cations, diradicals, and carbocations were considered, and a hybrid of carbocation and radical cation pathways was predicted to have the lowest overall barrier. American Chemical Society 2020-10-02 /pmc/articles/PMC7558033/ /pubmed/33073141 http://dx.doi.org/10.1021/acsomega.0c03735 Text en This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Chen, Shu-Sen
Tantillo, Dean J.
Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane Precursors
title Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane Precursors
title_full Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane Precursors
title_fullStr Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane Precursors
title_full_unstemmed Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane Precursors
title_short Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane Precursors
title_sort potential for ladderane (bio)synthesis from oligo-cyclopropane precursors
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7558033/
https://www.ncbi.nlm.nih.gov/pubmed/33073141
http://dx.doi.org/10.1021/acsomega.0c03735
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