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The heterogeneous nucleation of threading dislocations on partial dislocations in III-nitride epilayers

III-nitride compound semiconductors are breakthrough materials regarding device applications. However, their heterostructures suffer from very high threading dislocation (TD) densities that impair several aspects of their performance. The physical mechanisms leading to TD nucleation in these materia...

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Autores principales: Smalc-Koziorοwska, J., Moneta, J., Chatzopoulou, P., Vasileiadis, I. G., Bazioti, C., Prytz, Ø., Belabbas, I., Komninou, Ph., Dimitrakopulos, G. P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7566635/
https://www.ncbi.nlm.nih.gov/pubmed/33060651
http://dx.doi.org/10.1038/s41598-020-74030-y
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author Smalc-Koziorοwska, J.
Moneta, J.
Chatzopoulou, P.
Vasileiadis, I. G.
Bazioti, C.
Prytz, Ø.
Belabbas, I.
Komninou, Ph.
Dimitrakopulos, G. P.
author_facet Smalc-Koziorοwska, J.
Moneta, J.
Chatzopoulou, P.
Vasileiadis, I. G.
Bazioti, C.
Prytz, Ø.
Belabbas, I.
Komninou, Ph.
Dimitrakopulos, G. P.
author_sort Smalc-Koziorοwska, J.
collection PubMed
description III-nitride compound semiconductors are breakthrough materials regarding device applications. However, their heterostructures suffer from very high threading dislocation (TD) densities that impair several aspects of their performance. The physical mechanisms leading to TD nucleation in these materials are still not fully elucidated. An overlooked but apparently important mechanism is their heterogeneous nucleation on domains of basal stacking faults (BSFs). Based on experimental observations by transmission electron microscopy, we present a concise model of this phenomenon occurring in III-nitride alloy heterostructures. Such domains comprise overlapping intrinsic I(1) BSFs with parallel translation vectors. Overlapping of two BSFs annihilates most of the local elastic strain of their delimiting partial dislocations. What remains combines to yield partial dislocations that are always of screw character. As a result, TD nucleation becomes geometrically necessary, as well as energetically favorable, due to the coexistence of crystallographically equivalent prismatic facets surrounding the BSF domain. The presented model explains all observed BSF domain morphologies, and constitutes a physical mechanism that provides insight regarding dislocation nucleation in wurtzite-structured alloy epilayers.
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spelling pubmed-75666352020-10-19 The heterogeneous nucleation of threading dislocations on partial dislocations in III-nitride epilayers Smalc-Koziorοwska, J. Moneta, J. Chatzopoulou, P. Vasileiadis, I. G. Bazioti, C. Prytz, Ø. Belabbas, I. Komninou, Ph. Dimitrakopulos, G. P. Sci Rep Article III-nitride compound semiconductors are breakthrough materials regarding device applications. However, their heterostructures suffer from very high threading dislocation (TD) densities that impair several aspects of their performance. The physical mechanisms leading to TD nucleation in these materials are still not fully elucidated. An overlooked but apparently important mechanism is their heterogeneous nucleation on domains of basal stacking faults (BSFs). Based on experimental observations by transmission electron microscopy, we present a concise model of this phenomenon occurring in III-nitride alloy heterostructures. Such domains comprise overlapping intrinsic I(1) BSFs with parallel translation vectors. Overlapping of two BSFs annihilates most of the local elastic strain of their delimiting partial dislocations. What remains combines to yield partial dislocations that are always of screw character. As a result, TD nucleation becomes geometrically necessary, as well as energetically favorable, due to the coexistence of crystallographically equivalent prismatic facets surrounding the BSF domain. The presented model explains all observed BSF domain morphologies, and constitutes a physical mechanism that provides insight regarding dislocation nucleation in wurtzite-structured alloy epilayers. Nature Publishing Group UK 2020-10-15 /pmc/articles/PMC7566635/ /pubmed/33060651 http://dx.doi.org/10.1038/s41598-020-74030-y Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Smalc-Koziorοwska, J.
Moneta, J.
Chatzopoulou, P.
Vasileiadis, I. G.
Bazioti, C.
Prytz, Ø.
Belabbas, I.
Komninou, Ph.
Dimitrakopulos, G. P.
The heterogeneous nucleation of threading dislocations on partial dislocations in III-nitride epilayers
title The heterogeneous nucleation of threading dislocations on partial dislocations in III-nitride epilayers
title_full The heterogeneous nucleation of threading dislocations on partial dislocations in III-nitride epilayers
title_fullStr The heterogeneous nucleation of threading dislocations on partial dislocations in III-nitride epilayers
title_full_unstemmed The heterogeneous nucleation of threading dislocations on partial dislocations in III-nitride epilayers
title_short The heterogeneous nucleation of threading dislocations on partial dislocations in III-nitride epilayers
title_sort heterogeneous nucleation of threading dislocations on partial dislocations in iii-nitride epilayers
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7566635/
https://www.ncbi.nlm.nih.gov/pubmed/33060651
http://dx.doi.org/10.1038/s41598-020-74030-y
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