Spectroscopic capture of a low-spin Mn(IV)-oxo species in Ni–Mn(3)O(4) nanoparticles during water oxidation catalysis

High-valent metal-oxo moieties have been implicated as key intermediates preceding various oxidation processes. The critical O–O bond formation step in the Kok cycle that is presumed to generate molecular oxygen occurs through the high-valent Mn-oxo species of the water oxidation complex, i.e., the...

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Detalles Bibliográficos
Autores principales: Park, Sunghak, Jin, Kyoungsuk, Lim, Hyung Kyu, Kim, Jin, Cho, Kang Hee, Choi, Seungwoo, Seo, Hongmin, Lee, Moo Young, Lee, Yoon Ho, Yoon, Sangmoon, Kim, Miyoung, Kim, Hyungjun, Kim, Sun Hee, Nam, Ki Tae
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7567882/
https://www.ncbi.nlm.nih.gov/pubmed/33067446
http://dx.doi.org/10.1038/s41467-020-19133-w

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7567882/
https://www.ncbi.nlm.nih.gov/pubmed/33067446
http://dx.doi.org/10.1038/s41467-020-19133-w

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