Synthesis and Reactivity of Fluorinated Triaryl Aluminum Complexes

[Image: see text] The addition of the Grignard 3,4,5-Ar(F)MgBr to aluminum(III) chloride in ether generates the novel triarylalane Al(3,4,5-Ar(F))(3)·OEt(2). Attempts to synthesize this alane via transmetalation from the parent borane with trimethylaluminum gave a dimeric structure with bridging met...

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Detalles Bibliográficos
Autores principales: Ould, Darren M. C., Carden, Jamie L., Page, Rowan, Melen, Rebecca L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7581293/
https://www.ncbi.nlm.nih.gov/pubmed/32869993
http://dx.doi.org/10.1021/acs.inorgchem.0c01076

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7581293/
https://www.ncbi.nlm.nih.gov/pubmed/32869993
http://dx.doi.org/10.1021/acs.inorgchem.0c01076

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