Cargando…
Synthesis and Reactivity of Fluorinated Triaryl Aluminum Complexes
[Image: see text] The addition of the Grignard 3,4,5-Ar(F)MgBr to aluminum(III) chloride in ether generates the novel triarylalane Al(3,4,5-Ar(F))(3)·OEt(2). Attempts to synthesize this alane via transmetalation from the parent borane with trimethylaluminum gave a dimeric structure with bridging met...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7581293/ https://www.ncbi.nlm.nih.gov/pubmed/32869993 http://dx.doi.org/10.1021/acs.inorgchem.0c01076 |