Markovnikov-Type Hydrotrifluoromethylchalcogenation of Unactivated Terminal Alkenes with [Me(4)N][XCF(3)] (X = S, Se) and TfOH

The first Markovnikov-type hydrotrifluoromethylselenolation of unactivated terminal alkenes with the readily accessible [Me(4)N][SeCF(3)] reagent and the superacid TfOH is reported. The reaction proceeded at room temperature under catalyst- and additive-free conditions to give the branched trifluoro...

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Detalles Bibliográficos
Autores principales: Shi, Jin, Zhang, Cheng-Pan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7582815/
https://www.ncbi.nlm.nih.gov/pubmed/33022964
http://dx.doi.org/10.3390/molecules25194535

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7582815/
https://www.ncbi.nlm.nih.gov/pubmed/33022964
http://dx.doi.org/10.3390/molecules25194535

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