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Allylic Amination of Alkenes with Iminothianthrenes to Afford Alkyl Allylamines
[Image: see text] Allylic C–H amination is currently accomplished with (sulfon)amides or carbamates. Here we show the first allylic amination that can directly afford alkyl allylamines, enabled by the reactivity of thianthrene-based nitrogen sources that can be prepared from primary amines in a sing...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7584367/ https://www.ncbi.nlm.nih.gov/pubmed/33001638 http://dx.doi.org/10.1021/jacs.0c08248 |