Crystal Structure and Physical Properties of the Cage Compound Hf(2)B(2–2δ)Ir(5+δ)

[Image: see text] Hf(2)B(2–2δ)Ir(5+δ) crystallizes with a new type of structure: space group Pbam, a = 5.6300(3) Å, b = 11.2599(5) Å, and c = 3.8328(2) Å. Nearly 5% of the boron pairs are randomly replaced by single iridium atoms (Ir(5+δ)B(2–2δ)). From an analysis of the chemical bonding, the crysta...

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Detalles Bibliográficos
Autores principales: Sichevych, Olga, Flipo, Sever, Ormeci, Alim, Bobnar, Matej, Akselrud, Lev, Prots, Yurii, Burkhardt, Ulrich, Gumeniuk, Roman, Leithe-Jasper, Andreas, Grin, Yuri
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7586331/
https://www.ncbi.nlm.nih.gov/pubmed/32946694
http://dx.doi.org/10.1021/acs.inorgchem.0c02073

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7586331/
https://www.ncbi.nlm.nih.gov/pubmed/32946694
http://dx.doi.org/10.1021/acs.inorgchem.0c02073

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